Adding New Table Constraints
Go Up to Using ALTER TABLE
You can use ALTER TABLE to add a new table-level constraint. The syntax is:
ALTER TABLE name ADD [CONSTRAINT constraint] <tconstraint_opt>;
where <tconstraint_opt> is a PRIMARY KEY, FOREIGN KEY, UNIQUE, or CHECK constraint. For example:
ALTER TABLE EMPLOYEE ADD CONSTRAINT DEPT_NO UNIQUE(PHONE_EXT);